1. A summary about AC-Calorimetric measurements at High Pressure and Low Temperatures appeared in Adv. Phys. Solid State, 43, 889 (2003)
  2. The use of different high pressure technqiues in the investigation of various systems is desrcibed in Strongly correlated electron systems under high pressure: structural, magnetic, and superconducting phase transitions by H. Wilhelm, Habiliation Thesis, University Geneva, Mai 1999

Application to strongly correlated electron systems


1.) Heavy Fermions:

The application of external pressure on metals with strong correlations is an established technique to tune their ground state properties. The electronic interactions in heavy-Fermion (HF) compounds can be influenced in such a way that high pressure favors the Kondo interaction in Ce-compounds and the RKKY interaction in Yb-systems. Thus, pressure suppresses (favors) long range magnetic order and enhances (weakens) the screening of the localized 4f-electrons. If both interactions are of similar strength in the vicinity of a critical pressure often a deviation from the Fermi-liquid (FL) behavior is observed and some Ce-compounds even attain a superconducting ground state. More information about this topic can be found in the article by D. Jaccard et al., Physica B 259-261, 1 (1999).
 
 
 
 

Some examples of thoroughly investigated systems:

 CePd2+xGe2-x

Calorimetric and transport investigations of CePd2+xGe2-x  up to 22 GPa

Alternating current calorimetry at very high pressure and low temperature

Phys. Rev. B 66, 064428 (2002) and
cond-mat/0204559 

J. Phys.: Cond. Mater 14, 10683 (2002)

 CeRu2Ge2 Probing the phase diagram of CeRu2Ge2 by thermopower at high pressure

Detailed investigations of the magnetic phase diagram


Transport properties at high pressure
PRB 69, 214408 (2004), cond-mat/0402187

Phys. Rev. B
56, 3651 (1999)

Solid State Commun.
106, 239 (1998)
Physica B 259-261, 79 (1999)

CePd2Si2
Pressure-induced superconductivity Solid State Commun. 112, 617 (1999)
 CeCu5Au From an antiferromagnet to a heavy-fermion system: CeCu5Au under high pressure
 
 

Pressure-induced residual resistivity anomaly in CeCu5Au 

Sci. Techn. High Pressure, Proceedings
of AIRAPT 17, ed. M.H. Manghnani, 
W.J. Nellis and M.F. Nicol, Universities
Press, Hyderabad, India, p. 697 (2000)

J. Phys.: Cond. Matter 13, L329 (2001)


 YbCu2Si2

Pressure-induced magnetically ordered Kondo lattice state in YbCu2Si2
Eur. Phys. J. B 6, 5 (1998)

 YbInAu & YbCuAl 
Electrical resistivity of YbInAu and YbCuAl at high pressure Solid State Commun. 108, 279 (1998)
YbRh2(Si0.95Ge0.05)2
The break-up of heavy electrons at a quantum critical point
Nature 424, 524 (2003)


   
 

2.) 1D-organic compounds

The existence of a common border between the superconducting (SC) ground state and the insulating phase of spin density wave (SDW) nature, was recognized as a remarkable property of the phase diagram of the Bechgaard salt (TMTSF)2PF6. It belongs to a broad family of isostructural compounds (TM)2X, where the flat organic molecule TM is either tetramethyltetraselenafulvalene (TMTSF) or tetramethyltetrathiafulvalene (TMTTF). Here X denotes a monovalent anion such as PF6, AsF6, ClO4 or B. In the crystal, these molecules form stacks separated by chains of anions X. The overlap between the electron clouds of neighboring TM molecules along the stacking direction (parallel the a-axis) is about 10 (500) times larger than that between the stacks in the transverse b-(c-)direction. Provided that the longitudinal overlap is large compared to the on--site Coulomb repulsion, these organic materials become conducting with a pronounced one dimensional (1-D) character. The 1-D character of the Fermi surface of (TMTSF)2PF6, the presence of a spin-Peierls (SP) transition instead of the usual Peierls instability as well as the existence of enhanced antiferromagnetic (AF) fluctuations at low temperature, evidenced by NMR relaxation experiments, raised several questions about the mechanism responsible for superconductivity in organic conductors. Since 1-D physics is a relevant concept in these low dimensional systems, SDW and electron-electron pairing can develop simultaneously at low temperature in the interacting electron gas. A cross-over from SDW to SC correlations could possibly be achieved through a small variation of the coupling constants either by applying pressure or changing X. Furthermore, the nuclear spin-lattice relaxation rate data of (TMTSF)2PF6 suggest that SDW correlations prevail at low temperature even under pressure when superconductivity is stabilized.

The experimental and theoretical results are reported in:
D. Jaccard et al., J. Phys.: Cond. Matter 13, L89 (2001); From spin-Peierls to superconductivity:(TMTTF)2PF6 under high pressure
H. Wilhelm et al., Eur. Phys. J. B 21, 175 (2001); The case of universality of the phase diagram of the Fabre and Bechgaard salts

H. Wilhelm et al. in Frontiers of High Pressure Research II: Application of High Pressure to Low Dimensional Novel Electronic Materials, ed. H.D. Hochheimer et al. NATO Sciences Series II, Vol 48, Kluwer Academic Press, Dordrecht, p 423 (2001); Pressure-induced superconductivity in the spin-Peierls compound (TMTTF)2PF6


3.) High-Tc compounds and related cuprates
 
 

Influence of pressure on Tc and structural properties

 Ln2-xNdxCuO
 (Ln=La and Pr)

Pressure-induced Structural Phase Transitions in Ln2-xNdxCuO4 for
Ln=La (0.6<=x<=2) and Ln=Pr (x=0)

 

Pressure Induced Structural Phase Transition in Pr2CuO4
 
 
 

Influence of pressure on the crystal structure of Nd2CuO4

Pressure Induced Structural Phase Transition in the Solid-Solution
La2-xNdxCuO4 for x = 0.6, 0.7, 1.2, and 1.5

J. Solid State Chem. 151, 231 (2000)
 
 

Sci. Techn. High Pressure, Proceedings
of AIRAPT 17, ed. M.H. Manghnani, 
W.J. Nellis and M.F. Nicol, Universities
Press, Hyderabad, India, p. 740 (2000)

J. Mater. Chem. 8, 2729 (1998)

J. Solid State Chem. 126, 88 (1996)
 


 Tl0.5Pb0.5Sr2Ca1-xYxCu2O7
Pressure dependence of the superconducting critical temperature of ~
Phys. Rev. B 55, 11832 (1997)

 HgBa2Can-1CunO2n+2+y
(n=3,4)
Pressure dependence of the superconducting critical temperature of ~
up to 30 GPa

Phys. Rev. B 54, 4265 (1996)

 K2NiF4

Effect of pressure on the 2-magnon Raman scattering in K2NiF
V. V. Struzhkin et al.
Mater. Sci. Eng. A 168, 103 (1993)




last update june 2004