Mössbauer spectroscopy - P. Adler
Mössbauer spectroscopy is based on the recoil-free nuclear resonance absorption of γ radiation. This so-called Mössbauer effect was discovered in 1958 by Rudolf L. Mößbauer (1929 – 2011) within the framework of his PhD thesis. He obtained the Nobel prize in physics in 1961.
The application of Mössbauer spectroscopy in solid state and materials research takes advantage of the hyperfine interactions, i.e. the interactions between the electronic shell and the nuclear charge distribution which are sensitive to the chemical environment. The most important parameters extracted from the spectra are the isomer shift, the quadrupole splitting, and the magnetic hyperfine field. Mössbauer spectroscopy is a local probe which supplements the information from scattering techniques and yields information on oxidation states and chemical bonding, coordination environments, magnetic ordering phenomena, and dynamical effects.
At present one Mössbauer measuring station for 57Fe Mössbauer spectroscopy is available which consists of a WissEl Mössbauer spectrometer, a 57Co/Rh source, and a Janis closed cycle refrigerator cryostat (SHI-850-5) for experiments between 5 and 300 K.
Several materials of contemporary interest in solid state and materials science are studied, for instance iron-based superconductors like FeSe, magnetic Heusler alloys, and transition metal oxides, in particular double perovskites like the magnetically frustrated antiferromagnet Sr2FeOsO6.